01493nam a2200253Ia 4500 TVU_12328 210423s9999 xx 000 0 und d 0198511000 978-0198511007 eng 541.34 B512 Buncel, E. The E. Buncel, R.A. Stairs, H. Wilson. Oxford,New York University Press 2003 ix, 159 p. 26 cm The book begins with a summary of essential thermodynamic and kinetic facts, emphasizing aspects of these fields, where relevant, to reactions in solution. Chapter 2 introduces the reader to the role of the solvent purely as a medium, touching on early theories based on electrostatic considerations (Born and Kirkwood-Onsager) and the solubility parameter (Hildebrand). Chapter 3 discusses the role of solvent as an active participant, chiefly through hydrogen bonding, Brứnsted-Lowry and Lewis acid-base interactions, including hard and soft acids and bases. The ability of solvents to serve as media for oxidation and reduction is also touched upon. There then follows a chapter on chemometrics; the application of statistical methods to chemical phenomena and spectra, chiefly linear free energy correlations and principal component analysis Solvation; Chemical reactions E. Buncel; R.A. Stairs; H. Wilson. Trung tâm Học liệu Trường Đại học Trà Vinh