COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION

Low-cost nanoscale copper hexacyanoferrate (CuHF), a good selective adsorbent for cesium (Cs+) removal, was prepared using the chemical co-precipitation method. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), and high-resolution tr...

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Những tác giả chính:	Nguyễn, Đình Trung, Trương, Đông Phương, Lê, Vũ Trâm Anh, Kiều, Thị Đan Thy, Nguyễn, Trần Thúy Hồng, Ning, Ping, Đường, Thị Hương Giang, Hồ, Kim Dân
Định dạng:	Journal article
Ngôn ngữ:	English
Được phát hành:	2022
Những chủ đề:	Adsorption, Cesium, Copper hexacyanoferrate, Strontium.
Truy cập trực tuyến:	http://scholar.dlu.edu.vn/handle/123456789/1184 https://doi.org/10.37569/DalatUniversity.11.4.901(2021)
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id	oai:scholar.dlu.edu.vn:123456789-1184
record_format	dspace
institution	Thư viện Trường Đại học Đà Lạt
collection	Thư viện số
language	English
topic	Adsorption, Cesium, Copper hexacyanoferrate, Strontium.
spellingShingle	Adsorption, Cesium, Copper hexacyanoferrate, Strontium. Nguyễn, Đình Trung Trương, Đông Phương Lê, Vũ Trâm Anh Kiều, Thị Đan Thy Nguyễn, Trần Thúy Hồng Ning, Ping Đường, Thị Hương Giang Hồ, Kim Dân COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION
description	Low-cost nanoscale copper hexacyanoferrate (CuHF), a good selective adsorbent for cesium (Cs+) removal, was prepared using the chemical co-precipitation method. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), and high-resolution transmission electron microscopy (HR-TEM) were conducted to determine the CuHF morphology. Copper hexacyanoferrate, Cu13[Fe(CN)6]14.(2K).10H2O, has a cubic structure (space group F-43m) in the range of 10-30 nm and a Brunauer-Emmett-Teller (BET) surface area of 462.42 m2/g. The removal of Cs+ and Sr2+ is dependent on pH; the maximum adsorption capacity (qmax) of CuHF is achieved at a pH = 6. From the Langmuir model, qmax = 143.95 mg/g for Cs+ and 79.26 mg/g for Sr2+, respectively. At high concentrations, Na+, Ca2+, and K+ ions have very little effect on Cs+ removal, and Na+ and K+ ions have a higher affinity for removing Sr2+ than Ca2+ at all concentrations. CuHF has a high affinity for alkaline cations in the order: Cs+ > K+ > Na+ > Ca2+ > Sr2+, as proposed and discussed.
format	Journal article
author	Nguyễn, Đình Trung Trương, Đông Phương Lê, Vũ Trâm Anh Kiều, Thị Đan Thy Nguyễn, Trần Thúy Hồng Ning, Ping Đường, Thị Hương Giang Hồ, Kim Dân
author_facet	Nguyễn, Đình Trung Trương, Đông Phương Lê, Vũ Trâm Anh Kiều, Thị Đan Thy Nguyễn, Trần Thúy Hồng Ning, Ping Đường, Thị Hương Giang Hồ, Kim Dân
author_sort	Nguyễn, Đình Trung
title	COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION
title_short	COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION
title_full	COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION
title_fullStr	COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION
title_full_unstemmed	COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION
title_sort	copper hexacyanoferrate (ii): synthesis, characterization, and cesium, strontium adsorbent application
publishDate	2022
url	http://scholar.dlu.edu.vn/handle/123456789/1184 https://doi.org/10.37569/DalatUniversity.11.4.901(2021)
_version_	1768305959578370048
spelling	oai:scholar.dlu.edu.vn:123456789-11842022-10-06T09:04:11Z COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION Nguyễn, Đình Trung Trương, Đông Phương Lê, Vũ Trâm Anh Kiều, Thị Đan Thy Nguyễn, Trần Thúy Hồng Ning, Ping Đường, Thị Hương Giang Hồ, Kim Dân Adsorption, Cesium, Copper hexacyanoferrate, Strontium. Low-cost nanoscale copper hexacyanoferrate (CuHF), a good selective adsorbent for cesium (Cs+) removal, was prepared using the chemical co-precipitation method. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), and high-resolution transmission electron microscopy (HR-TEM) were conducted to determine the CuHF morphology. Copper hexacyanoferrate, Cu13[Fe(CN)6]14.(2K).10H2O, has a cubic structure (space group F-43m) in the range of 10-30 nm and a Brunauer-Emmett-Teller (BET) surface area of 462.42 m2/g. The removal of Cs+ and Sr2+ is dependent on pH; the maximum adsorption capacity (qmax) of CuHF is achieved at a pH = 6. From the Langmuir model, qmax = 143.95 mg/g for Cs+ and 79.26 mg/g for Sr2+, respectively. At high concentrations, Na+, Ca2+, and K+ ions have very little effect on Cs+ removal, and Na+ and K+ ions have a higher affinity for removing Sr2+ than Ca2+ at all concentrations. CuHF has a high affinity for alkaline cations in the order: Cs+ > K+ > Na+ > Ca2+ > Sr2+, as proposed and discussed. 11 4 76-97 2022-10-06T09:04:06Z 2022-10-06T09:04:06Z 2021-10-29 Journal article Bài báo đăng trên tạp chí trong nước (có ISSN), bao gồm book chapter http://scholar.dlu.edu.vn/handle/123456789/1184 https://doi.org/10.37569/DalatUniversity.11.4.901(2021) en Dalat University Journal of Science 0866-787X Aguila, B., Banerjee, D., Nie, Z., Shin, Y., Ma, S., & Thallapally, P. K. (2016). Selective removal of cesium and strontium using porous frameworks from high level nuclear waste. 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COPPER HEXACYANOFERRATE (II): SYNTHESIS, CHARACTERIZATION, AND CESIUM, STRONTIUM ADSORBENT APPLICATION

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