Synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (II) nanoparticles
Trigonal zinc hexacyanoferrate (TZHF) nanoparticle adsorbents for effective caesium ion (Cs+) removal were prepared using the chemical coprecipitation method. The morphologies of zinc hexacyanoferrate (ZHF) were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD)...
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2022
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Truy cập trực tuyến: | http://scholar.dlu.edu.vn/handle/123456789/1196 https://doi.org/10.1016/j.jece.2021.106772 |
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oai:scholar.dlu.edu.vn:123456789-11962022-10-07T03:00:45Z Synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (II) nanoparticles Nguyễn, Đình Trung Ning, Ping Lê, Thị Hà Lan Hồ, Kim Dân caesiumzinc hexacyanoferrateadsorptionchemical co-precipitationion exchange Trigonal zinc hexacyanoferrate (TZHF) nanoparticle adsorbents for effective caesium ion (Cs+) removal were prepared using the chemical coprecipitation method. The morphologies of zinc hexacyanoferrate (ZHF) were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM), and energy-dispersive X-ray spectroscopy (EDS). These analyses confirmed that the trigonal structure of ZHF and surface area is 43.08 m2/g. Cs+ removal was dependent on pH, with the greatest adsorption occurring under near-neutral conditions, and the removal process decreased with increasing pH. The Langmuir model was determined to be suitable for describing the adsorption process of Cs+ by ZHF. The mechanism of Cs+ adsorption was examined by Total Reflection X-ray Fluorescence (TXRF) using the gallium internal standard. In addition, the main mechanism of Cs+ adsorption by the ion exchange process was proposed and discussed. 9 6 106772 2022-10-07T03:00:41Z 2022-10-07T03:00:41Z 2021-12-01 Journal article Bài báo đăng trên tạp chí thuộc ISI, bao gồm book chapter http://scholar.dlu.edu.vn/handle/123456789/1196 https://doi.org/10.1016/j.jece.2021.106772 en Journal of Environmental Chemical Engineering 2213-3437 Elsevier |
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caesiumzinc hexacyanoferrateadsorptionchemical co-precipitationion exchange |
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caesiumzinc hexacyanoferrateadsorptionchemical co-precipitationion exchange Nguyễn, Đình Trung Ning, Ping Lê, Thị Hà Lan Hồ, Kim Dân Synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (II) nanoparticles |
description |
Trigonal zinc hexacyanoferrate (TZHF) nanoparticle adsorbents for effective caesium ion (Cs+) removal were prepared using the chemical coprecipitation method. The morphologies of zinc hexacyanoferrate (ZHF) were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM), and energy-dispersive X-ray spectroscopy (EDS). These analyses confirmed that the trigonal structure of ZHF and surface area is 43.08 m2/g. Cs+ removal was dependent on pH, with the greatest adsorption occurring under near-neutral conditions, and the removal process decreased with increasing pH. The Langmuir model was determined to be suitable for describing the adsorption process of Cs+ by ZHF. The mechanism of Cs+ adsorption was examined by Total Reflection X-ray Fluorescence (TXRF) using the gallium internal standard. In addition, the main mechanism of Cs+ adsorption by the ion exchange process was proposed and discussed. |
format |
Journal article |
author |
Nguyễn, Đình Trung Ning, Ping Lê, Thị Hà Lan Hồ, Kim Dân |
author_facet |
Nguyễn, Đình Trung Ning, Ping Lê, Thị Hà Lan Hồ, Kim Dân |
author_sort |
Nguyễn, Đình Trung |
title |
Synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (II) nanoparticles |
title_short |
Synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (II) nanoparticles |
title_full |
Synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (II) nanoparticles |
title_fullStr |
Synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (II) nanoparticles |
title_full_unstemmed |
Synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (II) nanoparticles |
title_sort |
synthesis, characterization, and caesium adsorbent application of trigonal zinc hexacyanoferrate (ii) nanoparticles |
publisher |
Elsevier |
publishDate |
2022 |
url |
http://scholar.dlu.edu.vn/handle/123456789/1196 https://doi.org/10.1016/j.jece.2021.106772 |
_version_ |
1768305963667816448 |