Prussian Blue Analogues of A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+) and Their Composition-Dependent Sorption Performances towards Cs+, Sr2+, and Co2+
Investigation in radioactive contaminant removal from aqueous solutions has been considered essential upon unexpected nuclear accidents. In this report, we have successfully prepared Prussian blue analogues (PBAs) with different substituted cations (A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+)). The synthe...
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Investigation in radioactive contaminant removal from aqueous solutions has been considered essential upon unexpected nuclear accidents. In this report, we have successfully prepared Prussian blue analogues (PBAs) with different substituted cations (A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+)). The synthesized PBAs were characterized and employed for the removal of Cs+, Sr2+, and Co2+ as sorption models, which are commonly found in radioactive waste. Sorption examinations reveal that Cu2[Fe(CN)6] has the highest sorption capacity towards Cs+, Sr2+, and Co2+ compared with those of Co2[Fe(CN)6] and Ni2[Fe(CN)6]. This is mainly attributed to the cation-exchange ability of substituted metal within the framework of PBAs. The sorption mechanism is qualitatively and quantitatively supported by infrared spectroscopy (IR) and total reflection X-ray fluorescence spectroscopy analysis (TXRF). In addition, it was found that Cs+ is adsorbed most effectively by PBAs due to the size matching between Cs+ ions and the channel windows of PBAs. These findings are important for the design of sorbents with suitable ion-exchange capacity and selectivity toward targeted radioactive wastes. |
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Lê, Thị Hà Lan Nguyễn, An Sơn Nguyễn, Đình Trung Le, Thi Van Cam Cao, Hai Van Nguyen, Ngoc Bao Le, Thi Thao Phuong |
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Lê, Thị Hà Lan Nguyễn, An Sơn Nguyễn, Đình Trung Le, Thi Van Cam Cao, Hai Van Nguyen, Ngoc Bao Le, Thi Thao Phuong Prussian Blue Analogues of A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+) and Their Composition-Dependent Sorption Performances towards Cs+, Sr2+, and Co2+ |
author_facet |
Lê, Thị Hà Lan Nguyễn, An Sơn Nguyễn, Đình Trung Le, Thi Van Cam Cao, Hai Van Nguyen, Ngoc Bao Le, Thi Thao Phuong |
author_sort |
Lê, Thị Hà Lan |
title |
Prussian Blue Analogues of A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+) and Their Composition-Dependent Sorption Performances towards Cs+, Sr2+, and Co2+ |
title_short |
Prussian Blue Analogues of A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+) and Their Composition-Dependent Sorption Performances towards Cs+, Sr2+, and Co2+ |
title_full |
Prussian Blue Analogues of A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+) and Their Composition-Dependent Sorption Performances towards Cs+, Sr2+, and Co2+ |
title_fullStr |
Prussian Blue Analogues of A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+) and Their Composition-Dependent Sorption Performances towards Cs+, Sr2+, and Co2+ |
title_full_unstemmed |
Prussian Blue Analogues of A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+) and Their Composition-Dependent Sorption Performances towards Cs+, Sr2+, and Co2+ |
title_sort |
prussian blue analogues of a2[fe(cn)6] (a: cu2+, co2+, and ni2+) and their composition-dependent sorption performances towards cs+, sr2+, and co2+ |
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2022 |
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http://scholar.dlu.edu.vn/handle/123456789/1198 https://doi.org/10.1155/2021/5533620 |
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oai:scholar.dlu.edu.vn:123456789-11982022-10-07T08:37:24Z Prussian Blue Analogues of A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+) and Their Composition-Dependent Sorption Performances towards Cs+, Sr2+, and Co2+ Lê, Thị Hà Lan Nguyễn, An Sơn Nguyễn, Đình Trung Le, Thi Van Cam Cao, Hai Van Nguyen, Ngoc Bao Le, Thi Thao Phuong Investigation in radioactive contaminant removal from aqueous solutions has been considered essential upon unexpected nuclear accidents. In this report, we have successfully prepared Prussian blue analogues (PBAs) with different substituted cations (A2[Fe(CN)6] (A: Cu2+, Co2+, and Ni2+)). The synthesized PBAs were characterized and employed for the removal of Cs+, Sr2+, and Co2+ as sorption models, which are commonly found in radioactive waste. Sorption examinations reveal that Cu2[Fe(CN)6] has the highest sorption capacity towards Cs+, Sr2+, and Co2+ compared with those of Co2[Fe(CN)6] and Ni2[Fe(CN)6]. This is mainly attributed to the cation-exchange ability of substituted metal within the framework of PBAs. The sorption mechanism is qualitatively and quantitatively supported by infrared spectroscopy (IR) and total reflection X-ray fluorescence spectroscopy analysis (TXRF). In addition, it was found that Cs+ is adsorbed most effectively by PBAs due to the size matching between Cs+ ions and the channel windows of PBAs. These findings are important for the design of sorbents with suitable ion-exchange capacity and selectivity toward targeted radioactive wastes. 2021 2022-10-07T08:37:21Z 2022-10-07T08:37:21Z 2021-03-27 Journal article Bài báo đăng trên tạp chí thuộc ISI, bao gồm book chapter http://scholar.dlu.edu.vn/handle/123456789/1198 https://doi.org/10.1155/2021/5533620 en Journal of Nanomaterials 1687-4110 J. 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