The preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells

Proton conducting membranes for fuel cell applications have been prepared by grafting of styrene onto pre-formed fluoropolymer films using electron beam or gamma radiation and then sulfonated. The influence of the preparation conditions and the role of the initial fluoropolymer has been investigate...

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Tác giả chính: Dương, Văn Đông
Định dạng: Bài viết
Ngôn ngữ:Vietnamese
Được phát hành: Trường Đại học Đà Lạt 2012
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Truy cập trực tuyến:https://scholar.dlu.edu.vn/thuvienso/handle/DLU123456789/33400
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spelling oai:scholar.dlu.edu.vn:DLU123456789-334002013-05-08T02:07:44Z The preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells Dương, Văn Đông Hóa phân tích Proton conducting membrane Proton conducting membranes for fuel cell applications have been prepared by grafting of styrene onto pre-formed fluoropolymer films using electron beam or gamma radiation and then sulfonated. The influence of the preparation conditions and the role of the initial fluoropolymer has been investigated. The investigation of PVDF and PTFE-graft-Styren films aimed to prepare the novel ion-exchanger and apply on electrolyte fuel cells. The grafting yields of PVDF and PTFE films gradually increased with the grafting time and then leveled off after 24 hours, which is independent of the irradiation condition. The concentration of free radical generated by Gamma-irradiation in PVDF and PTFE films increased with the irradiation dose in the range of 5 to 60 kGy. The free radicals generated in PVDF an d PTFE films decayed with storage time. 2012-12-03T07:33:16Z 2012-12-03T07:33:16Z 2005 Working Paper https://scholar.dlu.edu.vn/thuvienso/handle/DLU123456789/33400 vi Kỷ yếu Hội nghị khoa học – Sau đại học 2011;tr. 13-18 application/pdf Trường Đại học Đà Lạt
institution Thư viện Trường Đại học Đà Lạt
collection Thư viện số
language Vietnamese
topic Hóa phân tích
Proton conducting membrane
spellingShingle Hóa phân tích
Proton conducting membrane
Dương, Văn Đông
The preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells
description Proton conducting membranes for fuel cell applications have been prepared by grafting of styrene onto pre-formed fluoropolymer films using electron beam or gamma radiation and then sulfonated. The influence of the preparation conditions and the role of the initial fluoropolymer has been investigated. The investigation of PVDF and PTFE-graft-Styren films aimed to prepare the novel ion-exchanger and apply on electrolyte fuel cells. The grafting yields of PVDF and PTFE films gradually increased with the grafting time and then leveled off after 24 hours, which is independent of the irradiation condition. The concentration of free radical generated by Gamma-irradiation in PVDF and PTFE films increased with the irradiation dose in the range of 5 to 60 kGy. The free radicals generated in PVDF an d PTFE films decayed with storage time.
format Working Paper
author Dương, Văn Đông
author_facet Dương, Văn Đông
author_sort Dương, Văn Đông
title The preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells
title_short The preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells
title_full The preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells
title_fullStr The preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells
title_full_unstemmed The preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells
title_sort preparation of novel ion-exchange membranes by grafting of styrene onto pvdf and ptfe for application of polymer electrolyte fuel cells
publisher Trường Đại học Đà Lạt
publishDate 2012
url https://scholar.dlu.edu.vn/thuvienso/handle/DLU123456789/33400
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