Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition

An overview of the techniques used to examine supramolecular aggregates from a methodological point of view. Edited by a rising star in the community and an experienced author, this is a definitive survey of useful modern analytical methods for understanding supramolecular chemistry, from NMR to sin...

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Tác giả chính:	Schalley, Christoph
Định dạng:	Sách
Ngôn ngữ:	English
Được phát hành:	Wiley-VCH Verlag & Co. KGaA, 2012
Những chủ đề:	Analytical Methods
Truy cập trực tuyến:	http://scholar.dlu.edu.vn/thuvienso/handle/DLU123456789/33512
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id	oai:scholar.dlu.edu.vn:DLU123456789-33512
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institution	Thư viện Trường Đại học Đà Lạt
collection	Thư viện số
language	English
topic	Analytical Methods
spellingShingle	Analytical Methods Schalley, Christoph Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition
description	An overview of the techniques used to examine supramolecular aggregates from a methodological point of view. Edited by a rising star in the community and an experienced author, this is a definitive survey of useful modern analytical methods for understanding supramolecular chemistry, from NMR to single-molecule spectroscopy, from electron microscopy to extraction methods. A definitive study of this field touching many interdisciplinary areas such as molecular devices, biology, bioorganic chemistry, material science, and nanotechnology.
format	Book
author	Schalley, Christoph
author_facet	Schalley, Christoph
author_sort	Schalley, Christoph
title	Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition
title_short	Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition
title_full	Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition
title_fullStr	Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition
title_full_unstemmed	Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition
title_sort	analytical methods in supramolecular chemistry, 2nd, completely revised and enlarged edition
publisher	Wiley-VCH Verlag & Co. KGaA,
publishDate	2012
url	http://scholar.dlu.edu.vn/thuvienso/handle/DLU123456789/33512
_version_	1757674612301234176
spelling	oai:scholar.dlu.edu.vn:DLU123456789-335122014-01-19T08:26:16Z Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition Schalley, Christoph Analytical Methods An overview of the techniques used to examine supramolecular aggregates from a methodological point of view. Edited by a rising star in the community and an experienced author, this is a definitive survey of useful modern analytical methods for understanding supramolecular chemistry, from NMR to single-molecule spectroscopy, from electron microscopy to extraction methods. A definitive study of this field touching many interdisciplinary areas such as molecular devices, biology, bioorganic chemistry, material science, and nanotechnology. Preface XIII List of Contributors XV 1 Introduction 1 Lena Kaufmann and Christoph A. Schalley 1.1 Some Historical Remarks on Supramolecular Chemistry 1 1.2 The Noncovalent Bond: a Brief Overview 2 1.3 Basic Concepts in Supramolecular Chemistry 4 1.4 Conclusions: Diverse Methods for a Diverse Research Area 21 References 22 2 Quantitative Analysis of Binding Properties 27 Keiji Hirose 2.1 Theoretical Principles 27 2.2 A Practical Course of Binding Constant Determination by UV/Vis Spectroscopy 29 2.3 Practical Course of Action for NMR Spectroscopic Binding Constant Determination 44 2.4 Other Important Examples with Practical Actions of Data Treatment 53 2.5 Conclusion 59 References 66 3 Isothermal Titration Calorimetry in Supramolecular Chemistry 67 Franz P. Schmidtchen 3.1 Introduction 67 3.2 The Thermodynamic Platform 69 3.3 Acquiring Experimental Calorimetric Data 72 3.4 Extending the Measurement Range 88 3.5 Perspectives 100 Acknowledgment 100 References 101 4 Extraction Methods 105 Holger Stephan, Manja Kubeil, Kerstin Gloe, and Karsten Gloe 4.1 Introduction 105 4.2 The Extraction Technique 106 4.3 The Technical Process 108 4.4 The Extraction Equilibrium 109 4.5 Principles of Supramolecular Extraction 112 4.6 Examples of Supramolecular Extraction 114 4.7 Conclusions and Future Perspectives 124 Acknowledgments 125 References 125 5 Mass Spectrometry and Gas Phase Chemistry of Supramolecules 129 Dominik P. Weimann, Michael Kogej, and Christoph A. Schalley 5.1 Introduction 129 5.2 Instrumentation 130 5.3 Particularities and Limitations of Mass Spectrometry 141 5.4 Beyond Analytical Characterization: Tandem MS Experiments for the Examination of the Gas-Phase Chemistry of Supramolecules 143 5.5 Selected Examples 147 5.6 Conclusions 191 References 192 6 Diffusion NMR in Supramolecular Chemistry and Complexed Systems 197 Yoram Cohen, Liat Avram, Tamar Evan-Salem, Sarit Slovak, Noam Shemesh, and Limor Frish 6.1 Introduction 197 6.2 Concepts of Molecular Diffusion 198 6.3 Measuring Diffusion with NMR 198 6.4 Applications of Diffusion NMR in Supramolecular Chemistry: Selected Examples 209 6.5 Advantages and Limitations of High Resolution Diffusion NMR 259 6.6 Diffusion NMR and Chemical Exchange 260 6.7 Diffusion Modes and Signal Decay in Diffusion MR Experiments 265 6.8 Applications of Diffusion NMR in Complex Systems 269 6.9 Summary and Outlook 276 References 279 7 Photophysics and Photochemistry of Supramolecular Systems 287 Bernard Valeur, M´ario Nuno Berberan-Santos, Monique M. Martin, and Pascal Plaza 7.1 Introduction 287 7.2 Spectrophotometry and Spectrofluorometry 288 7.3 Time-Resolved Fluorescence Techniques 296 7.4 Fluorescence Anisotropy 311 7.5 Transient Absorption Spectroscopy 319 7.6 Concluding Remarks 332 References 334 8 Circular Dichroism Spectroscopy 337 Marie Urbanov´a and Petr Maloˇn 8.1 Basic Considerations 337 8.2 Measurement Techniques (Methodology of CD Measurement) 343 8.3 Processing of Circular Dichroism Spectra 350 8.4 Theory 356 8.5 Examples of Vibrational Circular Dichroism Applications 359 8.6 Concluding Remarks 363 Abbreviations 364 References 364 Contents to Volume 2 Preface XIII List of Contributors XV 9 Electrochemical Methods 371 Paola Ceroni, Alberto Credi, and Margherita Venturi 9.1 Introduction 371 9.2 Basic Principles of Electrochemistry 372 9.3 Overview of Electrochemical Techniques 378 9.4 Electrochemical Analysis of Supramolecular Systems 393 9.5 Selected Examples 396 9.6 Concluding Remarks 448 Acknowledgments 449 References 449 10 Crystallography and Crystal Engineering 459 Kari Rissanen 10.1 Introduction 459 10.2 Crystallography 460 10.3 Crystal Engineering 484 10.4 Methyl-Resorcinarene as a Crystal Engineering Target 487 10.5 Concluding Remarks 495 Acknowledgments 497 References 497 11 Scanning Probe Microscopy 499 Bianca A. Hermann and Regina Hoffmann-Vogel 11.1 Introduction: What Is the Strength of Scanning Probe Techniques? 499 11.2 How Do Scanning Probe Microscopes Work? 501 11.3 Which Molecules Can Be Studied? 533 11.4 What Results Have Been Obtained in the Field of Supramolecular Chemistry? 538 Acknowledgments 549 References 550 12 Single-Molecule Force Spectroscopy of Supramolecular Complexes 559 Tobias Schroeder, Volker Walhorn, Jochen Mattay, and Dario Anselmetti 12.1 Introduction and Motivation 559 12.2 Functionally Immobilizing Supramolecules 561 12.3 Supramolecular Interactions Investigated by AFM-SMFS 565 12.4 Summary and Outlook 603 Acknowledgments 604 References 604 13 Confocal Laser Scanning Microscopy: a Versatile Spectroscopic Tool for the Investigation of Molecular Gels 607 Anthony D’Al´eo, Andr´e Del Guerzo, and Fr´ed´eric Fages 13.1 Introduction: Molecular Gels 607 13.2 Methods Classically Used for the Characterization of Molecular Gels 608 13.3 Confocal Laser Scanning Microscopy (CLSM) 611 13.4 Applications of CLSM to the Study of Molecular Gels 613 13.5 Conclusion 624 References 624 14 Transmission Electron Microscopy (TEM) of Radiation Sensitive Supramolecular Architectures –Strategies for a Comprehensive Structure Characterization 629 Christoph Böttcher 14.1 Introduction 629 14.2 Instrumentation 631 14.3 Contrast in TEM 640 14.4 Sample Preparation 650 14.5 Strategies and Examples to Characterize Supramolecular Structures by Complementary TEM Methods 660 Acknowledgment 698 References 699 Further Reading 709 15 The Characterization of Synthetic Ion Channels and Pores 711 Stefan Matile and Naomi Sakai 15.1 Introduction 711 15.2 Methods 713 15.3 Characteristics 719 15.4 Structural Studies 734 15.5 Concluding Remarks 738 Acknowledgment 739 References 739 16 Theoretical Methods for Supramolecular Chemistry 743 Barbara Kirchner and Markus Reiher 16.1 Introduction 743 16.2 A Survey of Theoretical Methods 746 16.3 Standard Classification of Intermolecular Interactions 766 16.4 Qualitative Understanding and Decomposition Schemes 772 16.5 General Mechanism for a Static, Step-Wise View on Host–Guest Recognition 777 16.6 Conclusions and Perspective 785 Acknowledgments 786 References 786 Index 795 2012-12-17T02:47:13Z 2012-12-17T02:47:13Z 2012 Book 978-3-527-32982-3 http://scholar.dlu.edu.vn/thuvienso/handle/DLU123456789/33512 en application/pdf Wiley-VCH Verlag & Co. KGaA,

Analytical Methods in Supramolecular Chemistry, 2nd, Completely Revised and Enlarged Edition

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