The

The book begins with a summary of essential thermodynamic and kinetic facts, emphasizing aspects of these fields, where relevant, to reactions in solution. Chapter 2 introduces the reader to the role of the solvent purely as a medium, touching on early theories based on electrostatic considerations...

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Chi tiết về thư mục
Tác giả chính: Buncel, E.
Tác giả khác: E. Buncel; R.A. Stairs; H. Wilson.
Ngôn ngữ:Undetermined
English
Được phát hành: Oxford,New York University Press 2003
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Các nhãn: Thêm thẻ
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Thư viện lưu trữ: Trung tâm Học liệu Trường Đại học Trà Vinh
Miêu tả
Tóm tắt:The book begins with a summary of essential thermodynamic and kinetic facts, emphasizing aspects of these fields, where relevant, to reactions in solution. Chapter 2 introduces the reader to the role of the solvent purely as a medium, touching on early theories based on electrostatic considerations (Born and Kirkwood-Onsager) and the solubility parameter (Hildebrand). Chapter 3 discusses the role of solvent as an active participant, chiefly through hydrogen bonding, Brứnsted-Lowry and Lewis acid-base interactions, including hard and soft acids and bases. The ability of solvents to serve as media for oxidation and reduction is also touched upon. There then follows a chapter on chemometrics; the application of statistical methods to chemical phenomena and spectra, chiefly linear free energy correlations and principal component analysis
Mô tả vật lý:ix, 159 p.
26 cm
số ISBN:0198511000
978-0198511007